(S)-(−)-1-Phenylethanaminium hexanoate
نویسندگان
چکیده
A binary mixture of (S)-(-)-1-phenyl-ethanamine and hexa-noic acid was allowed to react to form the title salt, C8H12N(+)·C6H11O2(-). This crystal contains a 1:1 stoichiometric mixture of the acid- and amine-derived species and displays a chiral structure with N-H⋯O hydrogen-bonded chains propagating along the c-axis direction.
منابع مشابه
(R)-1-Phenylethanaminium (S)-4-chloromandelate
The absolute configuration of the title complex, C(8)H(12)N(+)·C(8)H(6)ClO(3) (-) or [R-C(6)H(5)C(H)CH(3)NH(3)][S-4-ClC(6)H(4)C(H)(OH)CO(2)], has been confirmed by the structure determination. In the crystal structure, inter-molecular O-H⋯O and N-H⋯O hydrogen bonds form a two-dimensional network perpendicular to the c axis.
متن کامل(S)-(−)-1-Phenylethanaminium 4-(4,4-difluoro-1,3,5,7-tetramethyl-3a,4a-diaza-4-borata-s-indacen-8-yl)benzoate
The title compound, C(8)H(12)N(+)·C(20)H(18)BF(2)N(2)O(2) (-), crystallizes with a significant amount of void space [4.0 (5)%] in the unit cell. The structure displays N-H⋯O hydrogen bonding between the components. The plane formed by the benzoic acid moiety of the BODIPY-CO(2) (-) is twisted by 80.71 (6)° relative to the plane formed by the ring C and N atoms of the tetramethyldipyrrin portion...
متن کامل2-Carboxy-1-phenylethanaminium perchlorate
In the title compound, C(9)H(12)NO(2) (+)·ClO(4) (-), an intra-molecular N-H⋯O inter-action results in the formation of a six-membered ring having a twisted chair conformation. In the crystal structure, inter-molecular O-H⋯O, N-H⋯O and C-H⋯O inter-actions link the mol-ecules into a network. A weak C-H⋯π inter-action is also found.
متن کامل2-Phenylethanaminium 4-hydroxybenzoate
In the title salt, C8H12N(+)·C7H5O3 (-), the cation is disordered over two orientations with site occupancies of 0.565 (7) and 0.435 (7). In the anion, the carboxyl-ate group makes the dihedral angle of 4.19 (18)° with the benzene ring. In the crystal, the ions are connected by N-H⋯O and O-H⋯O hydrogen bonds, forming a three-dimensional network.
متن کامل(±)-Bis(1-carboxy-2-phenylethanaminium) hexafluorosilicate(VI)
The asymmetric unit of the title fluoro-silicate salt, 2C(9)H(12)NO(2) (+)·SiF(6) (2-), consists of a phenylalaninium cation and half of a fluorosilicate anion, the Si atom being located on an inversion center. In the crystal, all of the F atoms act as hydrogen-bond acceptors and link the cations through different graph-set motifs, forming layers developing parallel to (100).
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